GC/MS Analysis of Fatty Acids in Italian Dry Fermented Sausages
Angelo Liguori*, 1, Emilia Lucia Belsito1, Maria Luisa Di Gioia1, Antonella Leggio1, Francesca Malagrinò1, Emanuela Romio1, Carlo Siciliano1, Antonio Tagarelli2
Identifiers and Pagination:Year: 2015
First Page: 5
Last Page: 13
Publisher Id: TOFSJ-9-5
Article History:Received Date: 20/2/2014
Revision Received Date: 2/6/2014
Acceptance Date: 15/6/2014
Electronic publication date: 26/6/2015
Collection year: 2015
open-access license: This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 International Public License (CC-BY 4.0), a copy of which is available at: https://creativecommons.org/licenses/by/4.0/legalcode. This license permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.
The present investigation reports a study about the evolution, during ripening, of the fatty acid profile and the fatty acid composition in acylglycerols of three different fermented sausages industrially produced in the Calabria region (Southern Italy). Statistical analysis (ANOVA) was applied to the results obtained for the profiles to check all the differences between samples. The study comprised also an evaluation of the lipid oxidation level. All kind of sausages showed a free fatty acids profile in which the monounsaturated fatty acids were predominant, followed by saturated and polyunsaturated fatty acids. In acylglycerols, a low content in linoleic acid (approximately 2% of total methyl esters) was displayed, while that found in the free fatty acids profile was higher (approximately 17% of total FFAs). In addition, the generation of aldehydes through secondary lipid oxidation was clearly confirmed after long ripening period by classical qualitative colorimetric method supported by 1H NMR spectroscopy. The differences in fatty acids profiles observed in the free fatty acids and the acylglycerol fractions were certainly due to the high selectivity of lypase activity during the ripening.